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Sheng Wu Gong Cheng Xue Bao · Mar 2019
Review[Baeyer-Villiger monooxygenases in the biosynthesis of microbial secondary metabolites].
- Yangli Li, Xiaoyu Yang, Zixin Deng, and Dongqing Zhu.
- Key Laboratory of Combinatorial Biosynthesis and Drug Discovery, Ministry of Education, School of Pharmaceutical Sciences, Wuhan University, Wuhan 430071, Hubei, China.
- Sheng Wu Gong Cheng Xue Bao. 2019 Mar 25; 35 (3): 351-362.
AbstractBaeyer-Villiger monooxygenases, a well-studied class of flavin-dependent enzymes, catalyze the conversion of ketones to lactones or esters and the oxygenation of heteroatoms, which possesses great practical prospect in synthetic chemistry and biocatalysis. In this review, we focus on Baeyer-Villiger oxidations involved in biosynthesis of microbial secondary metabolites and discuss the characteristics of these Baeyer-Villiger oxidations and Baeyer-Villiger monooxygenases, to provide reference for the protein engineering of Baeyer-Villiger monooxygenases.
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